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        名稱:二茂鐵甲酸
         

        純度:99% 包裝:25kg/桶
        結構式
            

        CAS: 1271-42-7
        分子式:C11H10FeO2
        分子量: 230.04
         
        中文名稱: 二茂鐵甲酸
         
        英文名稱: ferrocenecarboxylic acid
                              ferrocene carboxylic acid
                              ferrocenecarboxylicacid
         
        性狀描述: 黃色粉末。熔點208-212℃。
         
        用途: 可用于不對稱有機合成催化劑,燃燒控制劑或調節劑,在高分子材料中也可作光敏劑,穩定劑和改良劑。

        其它信息:

        Material Safety Data Sheet 
        Ferrocenecarboxylic acid  二茂鐵甲酸
        Section 1 - Chemical Product and Company Identification 
        MSDS Name: Ferrocenecarboxylic acid 
        Catalog Numbers: 34823-0000, 34823-0010, 34823-0100 
        Synonyms: Carboxyferrocene 
        Company Identification:  Acros Organics BVBA
        Janssen Pharmaceuticalaan 3a
        2440 Geel, Belgium 
        Company Identification: (USA) Acros Organics
        One Reagent Lane
        Fair Lawn, NJ 07410 
        For information in the US, call:  800-ACROS-01
        For information in Europe, call: +32 14 57 52 11
        Emergency Number, Europe: +32 14 57 52 99
        Emergency Number US: 201-796-7100
        CHEMTREC Phone Number, US:  800-424-9300
        CHEMTREC Phone Number, Europe:  703-527-3887 
        Section 2 - Composition, Information on Ingredients 
        CAS# Chemical Name: % EINECS#
        1271-42-7 Ferrocenecarboxylic acid 97% 215-040-6
        Hazard Symbols: XN 
           
        Risk Phrases: 22 36/37/38 
        Section 3 - Hazards Identification 
        EMERGENCY OVERVIEW 
        Harmful if swallowed. Irritating to eyes, respiratory system and skin. 
        Potential Health Effects
        Eye: Causes eye irritation. 
        Skin: Causes skin irritation. May be harmful if absorbed through the skin. 
        Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. 
        Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. 
        Chronic: 
        Section 4 - First Aid Measures 
        Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. 
        Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. 
        Ingestion: Get medical aid. Wash mouth out with water. 
        Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. 
        Notes to Physician: Treat symptomatically and supportively. 
        Section 5 - Fire Fighting Measures 
        General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. 
        Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. 
        Section 6 - Accidental Release Measures 
        General Information: Use proper personal protective equipment as indicated in Section 8. 
        Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Do not let this chemical enter the environment. 
        Section 7 - Handling and Storage 
        Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation. 
        Storage: Store in a cool, dry place. Store in a tightly closed container. 
        Section 8 - Exposure Controls, Personal Protection 
        Engineering Controls: 
         Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. 
        Exposure Limits
         CAS# 1271-42-7:
         
        Personal Protective Equipment 
        Eyes: Wear chemical splash goggles. 
        Skin: Wear appropriate protective gloves to prevent skin exposure. 
        Clothing: Wear appropriate protective clothing to prevent skin exposure. 
        Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
         
        Section 9 - Physical and Chemical Properties 
         
        Physical State: Powder
        Color: yellow to orange - brown 
        Odor: Not available 
        pH: Not available 
        Vapor Pressure: Not available 
        Viscosity: Not available 
        Boiling Point: Not available 
        Freezing/Melting Point: 210 deg C(decom) 
        Autoignition Temperature: Not available 
        Flash Point: Not available 
        Explosion Limits: Lower: Not available
        Explosion Limits: Upper: Not available
        Decomposition Temperature: Not available
        Solubility in water: Not available
        Specific Gravity/Density: 
        Molecular Formula: C11H10FeO2 
        Molecular Weight: 229.91 
        Section 10 - Stability and Reactivity 
        Chemical Stability: Stable. 
        Conditions to Avoid: Incompatible materials, dust generation. 
        Incompatibilities with Other Materials Strong oxidizing agents. 
        Hazardous Decomposition Products Carbon monoxide, carbon dioxide, oxides of iron. 
        Hazardous Polymerization Will not occur. 
        Section 11 - Toxicological Information 
        RTECS#: CAS# 1271-42-7: None listed
         
        LD50/LC50: RTECS: Not available. 
        Carcinogenicity: Ferrocenecarboxylic acid - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
         
        Other: The toxicological properties have not been fully investigated. 
        Section 12 - Ecological Information 
        Other: Do not empty into drains.
         
        Section 13 - Disposal Considerations 
        Dispose of in a manner consistent with federal, state, and local regulations. 
        Section 14 - Transport Information 

         IATA  IMO  RID/ADR 
        Shipping Name:  Not regulated.  Not regulated.  Not regulated. 
        Hazard Class:    
        UN Number:    
        Packing Group:    

        Section 15 - Regulatory Information 
        European/International Regulations
        European Labeling in Accordance with EC Directives
        Hazard Symbols: XN 
        Risk Phrases:
        R 22 Harmful if swallowed. 
        R 36/37/38 Irritating to eyes, respiratory system and skin. 
         
        Safety Phrases:
        S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
        S 37/39 Wear suitable gloves and eye/face protection.  
         
        WGK (Water Danger/Protection)
        CAS# 1271-42-7: Not available

        TSCA
        CAS# 1271-42-7 is not listed on the TSCA Inventory. It is for research and development use only. 


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